Environmental Chemistry Environmental chemistry: It is the branch of chemistry that deals with the study of various chemical processes taking place in the various segments of the environment. Broadly speaking, it is the study of the sources, transportation, reactions, effects and the ultimate of the chemical species occurring in one or more segments of the environment. Components of Environment : Atmosphere: This comprises a blanket of gaseous layer around earth. Hydrosphere : This comprises about 96% of earth’s surface & includes all sources of water like oceans rivers lakes, glaciers, ground water etc. Lithosphere : It refers to earth’s solid crust containing the outer mineral cover. It comprises soil, minerals, organic matter etc. Biosphere: It refers to the domain of living organism in covalent with atmosphere hydrosphere as well as lithosphere. Environmental pollution...
CHEMISTRY - XI
(CLASSIFICATION OF ELEMENTS AND PERIODICITY OF PROPERTIES)
Full Marks 35 Time: 1:15 hr
MULTIPLE CHOICE QUESTIONS: 1X5=5
1. Which of the
following sets gives the correct order of atomic radius ?
(a) B<Al<Mg<Ca (b) Al<B<Ca<Mg (c) Mg<Al<B<Ca (d) Ca<Mg<Al<B
2. Among the
isoelectronic species K+, S2- ,Cl- and Ca2+
, the radii of ions decrease as :
(a) Ca2+>K+>Cl->S2- (b) Cl->S2->K+>Ca2+ (c) S2->Cl->K+>Ca2+ (d) K+>Ca2+>S2->Cl-
3. Which of the
following represents the correct order of ionization enthalpy ?
(a)
F<Cl<Br<I (b)
Te<Se<S<O (c)
Na<K<Rb<Cs (d)
Si<Al<Mg<Na
4. Which among the
following has the highest value of negative electron-gain enthalpy ?
(a) Ne (b) N (c) O (d) F
5. Which among the
following is most ionic ?
(a) CCl4 (b) SiCl4 (c)
PbCl4 (d) PbCl2
VERY SHORT ANSWER TYPE
QUESTIONS: 1X5=5
6. State modern
periodic law ?
7. What is meant
by covalent radius of an atom ?
8. What do you
mean by isoelectronic species ?
9. What is meant
by electronegativity of an element ?
10. The electronic
configuration of an element is 1S2 2S2 2P6 3S2
3P5 . Name the period and the group to which it belongs ?
SHORT ANSWER TYPE QUESTIONS: 2X5=10
11. The
electron-gain enthalpy of O is less negative than that of S Justify ?
12. Write the
provisional IUPAC names of the elements with atomic numbers 115 to 124.
13. Would you
expect the second electron gain enthalpy of O as positive , more negative or
less negative than the first ? justify your answer.
14. What do you
mean by diagonal relationship ?
15. Explain the
following :
(i) Radius of
cation is less than that of the atom.
(ii) Radius of
anion is more than that of the atom.
LONG ANSWER TYPE QUESTIONS: 3X5=15
16. Define
ionization enthalpy. Name the factors which influence its value.
17. What are the
major difference between metals and non-metals?
18. What is basic
difference between the terms electron gain enthalpy and electronegativity ?
19. Arrange the elements N,P,O and S in the
order of
(i) increasing
first ionisation enthalpy.
(ii) increasing
non-metallic character.
(iii) Trends in
electron gain enthalpy.
Give reason for
the arrangment assigned.
20. The first and
second ionization enthalpies(KJ mol-1) of a few elements designated by Roman
numerals are shown below.
first ionization enthalpy second ionization enthalpy
I 2372 5251
II 520 7300
III 900 1760
IV 1680 3380
Which of the following element is likely to be :
(i) a reactive
element (ii) a reactive
non-metal (iii) a noble gas (iv) a metal A that forms a stable binary
halide of the formula AX2 (X = halogen) ?
Thanks sir I really enjoyed to solve this paper...
ReplyDeleteBut I have a doubt in the question no. 1....
I know it really sounds ridiculous, but I'm unable to solve that one...
So please give me the answer of question no. 1 with justification...
Ans. 1 (a) boron is a 2nd period element so is size is smaller while calcium is 4th period element so it's size is larger among all elements.
DeleteIn case of Al and Mg the size of Al is smaller due to high effective nuclear charge.